Download and install ATI's propriatary drivers for linux, that should give you all of the functionality of your card, provided its a radeon 8500 or above.
You should be able to install the ATI driver using ubuntu and just plug it into the tv. I think it will just "work". There is also the ati control panel package that lets you do tv out: fglrx-control
This documentation makes it a lot more complicated than it needs to be, but here it is:
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